EEPROM having a peripheral integrated transistor with thick oxide

ABSTRACT

A process for manufacturing an integrated circuit provides for the formation of a matrix of floating-gate non-volatile memory cells having dual polysilicon levels, with the two polysilicon levels being isolated by a gate dielectric layer ( 4 ) and an interpoly dielectric layer ( 9 ) therebetween, and for the concurrent formation of one type of thick-oxide transistor ( 21 ) having an active area ( 7 ) in regions peripheral to the matrix. The process of the invention provides for removal, during the step of defining the first-level polysilicon ( 5 ), the polysilicon ( 5 ) from the active area ( 7 ) of the thick-oxide transistor ( 21 ), so that the gate oxide of the transistor ( 21 ) results from the superposition of the first ( 4 ) and second ( 9 ) dielectric layers.

This application is a Divisional application of Ser. No. 08/840,327 filed Apr. 28, 1997.

FIELD OF THE INVENTION

This invention relates to a process for manufacturing integrated circuits which include non-volatile memory cells and peripheral transistors.

BACKGROUND OF THE INVENTION

Most up-to-date applications of integrated circuits concern systems which are supplied voltages in the 3-volt range. Such systems often utilize semiconductor storage facilities of the non-volatile type. In order to retain the characteristics of these devices at low supply voltages, it has been necessary to employ thin oxides (160 Å-thick or less). However, it is well recognized that memories of the EPROM, EEPROM, FLASH types require high programming voltages (12V) which cannot be accommodated by such thin oxides. Accordingly, the requirement involves the concurrent provision of thick and thin oxides in one device, which burdens the process technology with at least one additional masking operation.

As for the peripheral transistors, these are incorporated in circuits outside the array of memory cells, such as array control logics or circuits, and are frequently expected to withstand high voltages, on the order of 12 to 15 volts. In describing this invention, reference will be made specifically to transistors of the MOS type.

Such transistors include an active dielectric, or gate dielectric, placed between the substrate and a gate made of an electrically conductive material, usually polysilicon. In general, the active dielectric consists of a layer of silicon oxide obtained by oxidation of the substrate at a high temperature.

PRIOR ART

Processes for manufacturing integrated structures which include non-volatile memory cells, i.e. cell matrices set up into rows and columns, using dual levels of polysilicon with a gate dielectric layer and an isolating interpoly dielectric layer therebetween, have been known and extensively used in the industry.

Such manufacturing processes may provide for a first masking and implanting step effective to define well regions having conductivity of a different type from that of the semiconductor substrate, in order to provide N-channel and P-channel devices on one chip. Conventional processes essentially utilize, therefore, one mask to define the active areas of the individual integrated devices (transistors, floating-gate memory cells, etc.). The process normally provides for an additional masking step, in order to form field isolation implants, that is, to have the semiconductor implanted in those zones where a thick oxide layer will be later grown to define and isolate the individual active areas.

The process may provide for an ATP (Anti-Punch Through) implantation of all those active areas that have the same type of conductivity. A relatively heavy threshold-raising implantation (EPM) is performed in the matrix area where the floating-gate memory cells are to be formed. A thin layer of gate oxide is then grown over the active areas. Subsequent to the depositing and doping of a first-level polysilicon layer (poly 1), a masking and etching step is usually carried out for a first definition of the first-level polysilicon that is to provide the floating gates for the memory cells.

A thin dielectric layer is next grown and/or deposited over the entire structure to isolate the two polysilicon levels (interpoly). This thin dielectric isolation layer may be a multiple layer, typically comprised of a first oxidation. layer, a thin second layer of deposited silicon nitride, and a third nitride oxidation layer (the so-called O.N.O. multi-layer). At this stage, a masking step is typically carried out in such processes using a mask commonly referred to as the “matrix mask”, thereby to remove the interpoly dielectric isolation layer from all over the surface except the area being occupied by the memory cells (matrix). Thereafter, a second-level doped polysilicon layer is deposited which, in the formation area of the floating-gate memory cells, will thus be isolated from the interpoly dielectric layer by the first-level polysilicon portions previously defined. On the other hand, the second layer of doped polysilicon will directly overlie the existing first-level layer of polysilicon, in areas outside the area being occupied by the memory cell matrix, that is the areas where the transistors and other external circuit devices are formed.

Conventional processes may also require a masking step specifically to perform an implantation, known as the LVS (Light Voltage Shift) implant, for slightly adjusting the threshold of standard enhancement transistors in the circuitry, with the channel areas of the so-called “natural” (or low threshold) transistors screened off the LVS implant. By an additional masking (poly 2) and etching step, the second-level polysilicon is defined which, in the matrix area, is terminated at the interpoly dielectric layer and, in the circuit area, also results in the underlying first-level polysilicon being defined, thereby defining the channel length of the transistors in the circuit.

A manufacturing process as described above is disclosed in prior Italian Patent Application No. 23737-A/84 and, inter alia, the corresponding patent publication GB-2,167,602, both in the name of this Applicant. It is intended that the contents of these prior publications be incorporated herein by reference, wherever appropriate.

What is needed is a process for forming non-volatile memory cells and thick-oxide peripheral transistors by a minimum number of steps, and accordingly, for lower production costs.

SUMMARY OF THE INVENTION

Accordingly, the present invention provides a process for manufacturing a thick-oxide transistor having an active area region in an integrated circuit which which also includes a matrix area of floating-gate non-volatile memory cells having dual polysilicon levels isolated from each other by a gate dielectric layer and an interpoly dielectric layer therebetween. The process comprises an optional step for defining well regions. The process further comprises at least one masking step for defining the active areas of individual integrated devices, a masking step for defining an implant in the matrix area, a masking step for defining a first-level polysilicon to form floating-gate structures for the memory cells within the matrix area, a matrix masking step for etching away said interpoly dielectric layer from areas outside the matrix area, at least one masking step for defining a second-level polysilicon, and wherein the masking step for defining the first-level polysilicon includes removal of the polysilicon from the active area region of the thick-oxide transistor.

The present invention also provides an integrated circuit on a semiconductor material substrate. The integrated circuit comprises at least one matrix of non-volatile memory cells, wherein each cell has an electrically conductive floating gate, formed by a masking operation f or defining a first-level polysilicon layer, which is isolated electrically between a first dielectric layer of silicon oxide and a second dielectric layer including at least one layer of silicon oxide; and further comprising in regions peripheral to the matrix, at least a first type of transistors including an active area region having a thick gate oxide, wherein said thick gate oxide of said transistors comprises said first and second dielectric layers.

The features of this invention will be more clearly apparent from the following detailed description of embodiments thereof, shown in the accompanying drawings by way of non-limiting examples.

BRIEF DESCRIPTION OF THE DRAWINGS

FIGS. 1-9 illustrate a process according to the invention;

FIG. 10 is a plan view of the profiles of the masks used to define the thick-oxide transistor structure in a process according to the invention.

FIG. 11 is a sectional view of the thick-oxide transistor structure taken along line A-A′ in FIG. 10.

FIG. 12 is a sectional view of the thick-oxide transistor structure taken along line B-B′ in FIG. 10, orthogonally with the section view of FIG. 11.

DETAILED DESCRIPTION OF A PREFERRED EMBODIMENT OF THE INVENTION

A process for forming memory cells and thick-oxide transistors in accordance with the invention will now be described with reference, in particular, to a preferred embodiment thereof, illustrated by FIGS. 1-9. These figures are sectional views, not drawn to scale, showing schematically the sequential process steps of forming a non-volatile memory cell, a thick-oxide MOS transistor, and a direct contact. The partial constructions of the cell, the transistor and the direct contact are denoted by the reference numerals 20, 21 and 22, respectively.

The basic construction of the memory cell 20 is that of all non-volatile memory cells, of either the EPROM, EEPROM or FLASH type, and comprised of a floating-gate MOS transistor. Thick-oxide transistor 21 is a MOS transistor formed in accordance with the invention. The process specifically referred to in this description is a process of the MOS type, preferably as carried out with CMOS technology. The process of this invention may include conventional steps of forming, in a semiconductor substrate having conductivity of a first type, well regions with a second type of conductivity.

The definition of active areas may be performed using a LOCOS (trademark of Philips, The Netherlands) method or PLANOX (Applicant's trademark) method, which may include an isolation implant for the areas where a thick layer of field oxide is to be grown to yield a structure like that shown in FIG. 1. In FIG. 1, reference 1 designates a monocrystalline semiconductor having a given type of conductivity on which the active areas are defined by isolating diffusions 2 and field oxide 3.

By an extensively used technique, a light implantation may be performed during this step at a high implanting energy, to provide an APT (Anti-Punch Through) implant, not shown to avoid overcrowded drawing figures. Also during this step, a relatively heavy implantation (EPM) is commonly performed, limited to the matrix area, by implanting a boron dosage of about 6.5×10¹² at 120 keV, for example. Unlike the APT implant, the latter implant is shown in the drawing figures as EPM. Again in conducting a standard process sequence, a thin oxide layer 4 of a first type, having a thickness of 100 to 120 Å, is then formed over the active areas, as shown in FIG. 2.

The process is continued with the deposition of a first polysilicon layer 5 (poly 1), which is suitably- doped with phosphorus (F), as shown in FIG. 3., This is followed by a masking/etching step carried out on the poly 1 to define the floating gate 6 structures within the matrix area, and in accordance with the invention, remove the first-level polysilicon layer 5 (poly 1) from an active area or region 7 of transistor 21, as shown schematically in FIG. 4.

As shown in FIG. 5, a thermal oxidation treatment is applied next which may also include intermediate steps of nitride deposition by a conventional technique to form a second type of oxide layer 9 serving as an interpoly isolation dielectric for the memory cell 20. This oxide layer 9 of the second type overlies the existing oxide layer 4 of the first type at the active area 7 of the transistor 21 and the contact area 8 farthest to the right in the figures. Thus, there will occur, in the active area 7 of the transistor 21, a superposition of two oxide layers, namely of the first-type oxide 4 and the second-type oxide 9. These oxide layers form, in accordance with the invention, a thick oxide whereon the transistor gate will then be formed. The thermal oxidation treatment also causes the dopant implanted during the EPM implantation step to be diffused, as marked symbolically in FIG. 5.

According to the invention, and as shown in FIG. 6, the so-called matrix mask is then formed to define a center or channel area of transistor 21, as shown on the left in the sectional views which illustrate the formation of the active area 7 of thick-oxide transistor 21. Upon removal of the matrix mask, therefore, the channel or active area 7 of the transistor 21 will be covered with a thick oxide layer of about 300 Å, resulting from the superposed oxide layers of the first and second types 4 and 9, respectively.

A second layer 11 of poly 2 polycrystalline silicon is deposited next, as shown in FIG. 7. This is followed by the formation of a mask 12 defining the second-level polycrystalline silicon or poly 2 as shown in FIG. 8. By etching away the polysilicon through the poly 2 mask 12, the gate structure of the thick-oxide transistor 21 is defined as illustrated by the sectional view of FIG. 8.

FIG. 9 is a sectional view showing the structure after the poly 2 mask is removed, and the source and drain regions of the integrated structures are implanted and diffused.

The architecture of the thick-oxide transistor 21 provided by the invention is fully illustrated in FIGS. 10, 11 and 12, which are respectively plan views of the related poly 1 and matrix and poly 2 active area masks, and two cross sections taken orthogonally through the transistor structure.

The poly 2 layer 11 over the thick-oxide transistor area is short-circuited to the poly 1 layer 5 by direct superposition on the latter, over the field oxide 3, as shown by section B-B′ in FIG. 12.

In practice, the present invention allows thick-oxide transistors to be made through the utilization of classic masking operations in a dual polysilicon level process (of the DPCC type), thereby avoiding the need for an additional masking step, such as is required instead in conventional processes used to also form thick-oxide transistors. The process of the present invention accomplishes the above without introducing difficulties at the production stage.

It should be understood that many changes and modifications may be made to the foregoing process for making non-volatile memory cells and thick-oxide transistors in accordance with the invention, without departing from the invention scope as defined in the appended claims 

What is claimed is:
 1. A circuit integrated on a semiconductor material substrate, comprising: at least one matrix of non-volatile memory cell transistors, wherein each memory cell transistor has an electrically conductive floating gate that is isolated electrically between a first dielectric layer and a second dielectric layer; and in regions peripheral to the matrix of non-volatile memory cells, at least one transistor having a thick gate dielectric comprising the first and second dielectric layers.
 2. The circuit of claim 1, wherein the second dielectric layer comprises a nitride layer and an oxide layer.
 3. The circuit according to claim 1, wherein the thick gate dielectric of the at least one transistor consists essentially of the first and second dielectric layers as formed for each memory cell transistor.
 4. The circuit of claim 1, wherein: in the at least one transistor, the second dielectric layer comprises a first oxide layer formed between the first dielectric layer and the semiconductor material substrate, and a nitride layer formed over the first dielectric layer.
 5. The circuit of claim 4, wherein the second dielectric layer further comprises a second oxide layer formed over the nitride layer.
 6. An integrated memory device including a matrix area of floating-gate memory cell transistors and a peripheral area of at least one peripheral transistor, the memory device comprising: a first dielectric layer disposed over the peripheral area to form a portion of the gate dielectric of the peripheral transistor, and over the matrix area to form a gate dielectric of the memory cell transistors; a first-level polysilicon layer disposed over the matrix area to form floating-gate regions for the memory cell transistors; an interpoly dielectric layer disposed over the peripheral area to form the gate dielectric of the peripheral transistor with the first dielectric layer, and disposed over the matrix area; and a second-level polysilicon layer disposed over the matrix area to form a control gate of the memory cell transistors, and over the gate dielectric of the peripheral transistor to form the gate thereof.
 7. The memory device according to claim 6, wherein the interpoly dielectric layer over the peripheral area defines a channel area of the peripheral transistor.
 8. The memory device according to claim 6, wherein said peripheral transistor is a MOS transistor.
 9. The memory device according to claimed 6, wherein the first dielectric layer over the peripheral area of the peripheral transistor and over the matrix area of the memory cell transistor is substantially the same thickness.
 10. The memory device according to claim 6, wherein the gate dielectric of the peripheral transistor consists essentially of the first and interpoly dielectric layers.
 11. The integrated memory device of claim 6, wherein the interpoly dielectric layer comprises a nitride layer and a first oxide layer.
 12. The integrated memory device of claim 11, wherein the integrated memory device is formed over a semiconductor substrate, the first oxide layer is formed between the semiconductor substrate and the first dielectric layer, and the nitride layer is formed over the first dielectric layer.
 13. The integrated memory device of claim 12, wherein the second interpoly dielectric layer further comprises a second oxide layer formed over the nitride layer.
 14. An integrated circuit including at least one floating gate transistor and at least one single gate transistor having a single gate, comprising: an active area of the floating gate transistor and an active area of the single gate transistor defined over a semiconductor material; a first dielectric layer disposed over the active area of the floating gate transistor and the active area of the single gate transistor; a first polysilicon layer disposed over the active area of the floating gate transistor to form the floating gate of the floating gate transistor; a second dielectric layer disposed over the active area of the floating gate transistor and the single gate transistor, the second dielectric layer combining with the first dielectriclayer in the active area of the single gate transistor so as to form a single dielectric comprising the gate dielectric of the single gate transistor, the second dielectric layer forming an interpoly dielectric of the floating gate transistor; a second polysilicon layer disposed over the active area of the floating gate transistor and the single gate transistor so as to form the control gate of the floating gate transistor gate and the gate of the single gate transistor, respectively; and diffusion regions defined in the semiconductor material to form the source and drain regions of the single gate transistor.
 15. The integrated circuit of claim 14, wherein: the second dielectric layer includes a patterned second dielectric layer over the active area of the single gate transistor so as to define a channel region thereof.
 16. The integrated circuit of claim 14, wherein: the second dielectric layer disposed over the active area of the floating gate transistor comprises an interpolysilicon oxide layer therefor.
 17. The integrated circuit of claim 14, wherein: the first and second dielectric layers form a single gate oxide of the single gate transistor.
 18. The integrated circuit of claim 14, further including: a dopant implanted in the active area of the floating gate transistor and diffused into the semiconductor material.
 19. The integrated circuit of claim 14, wherein: the gate oxide formed by the combination of the first and second dielectric layers is approximately 300 Angstrom units thick.
 20. The integrated circuit of claim 14, wherein the first dielectric layer is substantially the same thickness over both the active area of the floating gate transistor and the active area of the single gate transistor.
 21. The integrated circuit of claim 14, wherein the single dielectric of the single gate transistor consists essentially of the first and second dielectric layers.
 22. The integrated circuit of claim 14, wherein the second dielectric layer comprises a nitride layer and a first oxide layer.
 23. The integrated circuit of claim 22, wherein the integrated circuit is formed over a semiconductor substrate, the first oxide layer is formed between the semiconductor substrate and the first dielectric layer, and the nitride layer is disposed over the first dielectric layer.
 24. The integrated circuit of claim 23, wherein the second interpoly dielectric layer further comprises a second oxide layer over the nitride layer.
 25. An integrated circuit including at least one memory cell transistor and a thick oxide transistor, comprising: an active area of the memory cell transistor and an active area of the thick oxide transistor over a semiconductor material; a first dielectric layer over the active area of the memory cell transistor and the thick oxide transistor, the first dielectric layer being formed on the semiconductor material and being the same for both the memory cell transistor and the thick oxide transistor; a first polysilicon layer over the active area of the memory cell transistor, the first polysilicon layer forming a first control terminal of the memory cell transistor; a second dielectric layer over the active area of the memory cell transistor and the thick oxide transistor, the second dielectric layer and the first dielectric layer in the active area of the thick oxide transistor forming a single gate oxide thereof; a second polysilicon layer over the active area of the memory cell transistor and the thick oxide transistor, the second polysilicon layer in the active area of the thick oxide transistor forming the gate thereof and the second polysilicon layer in the active area of the memory cell transistor forming a second control terminal thereof; and a plurality of regions defined in the semiconductor material so as to form the source and drain regions of the thick oxide transistor.
 26. The integrated circuit of claim 25, wherein: the second dielectric layer overlays the first polysilicon layer in the active area of the memory cell transistor; and the second polysilicon layer overlays the second dielectric layer in the active area of the memory cell transistor such that the first and second control terminals of the memory cell transistor are substantially vertically aligned relative to each other.
 27. The integrated circuit of claim 25, wherein: the second dielectric layer includes a patterned second dielectric layer over the active area of the thick oxide transistor so as to define the channel region thereof.
 28. The integrated circuit of claim 25, wherein: the gate oxide formed by the first and second dielectric layers is approximately 300 Angstrom units thick.
 29. The integrated circuit of claim 25, wherein the first dielectric layer is substantially the same thickness over both the active area of the memory cell transistor and the active area of the thick oxide transistor.
 30. The method according to claim 25, wherein the single gate oxide of the thick oxide transistor consists essentially of the first and second dielectric layers.
 31. The integrated circuit of claim 25, wherein the second dielectric layer comprises a nitride layer and a first oxide layer.
 32. An integrated circuit memory device formed in a semiconductor material, comprising: a first dielectric layer disposed over a first area and a second area of the semiconductor material so as to form a dielectric for a plurality of floating gate transistors in the first area and at least one thick dielectric transistor in the second area; a first-level polysilicon layer on the first dielectric layer over the first area so as to define floating-gate regions for the floating gate transistors within the first area; a second dielectric layer on the active area of the thick-oxide transistor and on the first-level polysilicon layer of the matrix area, the second dielectric layer being the same in both the thick-dielectric transistor and the matrix area, the combination of the first and second dielectric layers in the second area form the gate dielectric of the thick-oxide transistor, the second dielectric layer forming an interpoly dielectric layer for the floating gate transistors in the first area; and a second-level polysilicon layer on the gate dielectric of the thick-oxide transistor and on the second dielectric layer of the floating gate transistors, the second-level polysilicon layer, being the same on both the thick-oxide transistor and the floating gate transistors, the second-level polysilicon layer comprising the gate of the thick-oxide transistor.
 33. The integrated circuit memory device according to claim 32, wherein the first dielectric layer is an oxide layer.
 34. The integrated circuit memory device according to claim 32, wherein the first and second dielectric layers are different types of oxide layers.
 35. The integrated circuit memory device according to claim 32, wherein the first dielectric layer is a thickness of about 100 Angstroms to about 120 Angstroms.
 36. The integrated circuit memory device according to claim 32, wherein the first and second dielectric layers combine to form a thickness of about 300 Angstroms.
 37. The integrated circuit memory device according to claim 32, wherein the first-level polysilicon layer is doped with phosphorus.
 38. The integrated circuit memory device according to claim 32, wherein the first dielectric layer is substantially the same thickness over both the first area and the second area.
 39. The integrated circuit memory device according to claim 32, wherein the gate dielectric of the thick-oxide transistor consists essentially of the first and second dielectric layers.
 40. The integrated circuit memory device of claim 32, wherein the second dielectric layer comprises a nitride layer and a first oxide layer. 